Experimental Assessment of Local Demulsifiers for Crude Oil Emulsion Breaking: A Study on Jatropha curcas, Indigenous Materials, and their Blends

Authors

  • O Praise Agbabi Author

Keywords:

Crude oil emission, Jathrophia curcas, local materials demulsifiers, Separation efficiency, water recovery

Abstract

Crude oil emulsion is one of the most challenging problems plaguing the phases of oil and gas production. Crude oil emulsion stability causes high viscosity of crude oil which leads to challenges in pipeline transportation and processing. This paper investigated the effectiveness of locally sourced material as a demulsifier, where the stability crude oil emulsion of varying viscosity by using three different formulated local demulsifiers such as Jatropha curcas extract, local materials, and their blends were investigated. The laboratory experiment was carried out using Crude oil I, II and III, blend of Jatrophas curcas and local materials into Sample A (100% Jatropha curcas extract), B (6:4), C (1:1), D (4:6), E (3:7), F (2:8),  and G (100% local materials), at 60, 90, 120, 180, 240. 300, 360, 420 and 480 mins. The result generally showed that the lower the viscosity of crude oil the higher the water recovery (WR). Also, the demusifier blends had better WR when compared to without blends. Irrespective of the type of crude oil, demulsifier blends of equal ratio 1:1, 4:6, and 3:7 % led to maximum WR. For crude oil I, without delmusifier achieved 5.4 % WR, while Sample A had 86 % 77 % WR for Sample G at constant time of 480 mins, and 100 % WR for Sample D but at 36mins. Crude oil II, had WR of 4.0% at 480mins without demulsifier, Sample A, B, and D had water recovery of 79%, 72%, and 100% at 480 mins, respectively. Lower recoveries were observed for crude III majorly due to its higher viscous nature, as all samples had WR between 48.2 and 75%. This study has demonstrated that blend of locally formulated demulsifiers had better water separation capability.

Author Biography

  • O Praise Agbabi

    Department of Petroleum Engineering,

    Faculty of Engineering, Delta State University, Oleh Campus, Nigeria

References

Abdullah, M. M., & Al-Lohedan, H. A. (2020). Novel amphiphilic gemini ionic liquids based on consumed polyethylene terephthalate as demulsifiers for Arabian heavy crude oil. Fuel, 266, 117057.

Abdullah, M. M., & Al-Lohedan, H. A. (2021). Novel bio-based amphiphilic ionic liquids for the efficient demulsification of heavy crude oil emulsions. Molecules, 26 (20), 6119.

Adebanjo, F. O., & Aduroja, O. C. (2015). Development of Local Demulsifier for Water-In-Oil Emulsion Treatment. International Journal of Sciences: Basic and Applied Research (IJSBAR) Volume, 24, 301-320.

Alao, K. T., Alara, O. R., & Abdurahman, N. H. (2021). Trending approaches on demulsification of crude oil in the petroleum industry. Applied Petrochemical Research, 11(3), 281-293.

Al-Sabagh A. M., Nasser N. M., Khamis E. A., Abd-El-Raouf M. (2015): “Resolution of Water in Crude Oil Emulsion by Some Novel Aromatic Amine Polyesters”. Egyptian Journal of Petroleum; 24, 363–374.

Azubike, A. A., & Itohan, E. (2021). Prospects of Breaking Crude Oil Emulsions Using Demulsifier Formulated from Nicotiana tabacum Seed Oil, Leaf Extracts, and Stalk Ash Extracts.

Boisa, N., Maduelosi, N. J., & Ogbuu, A. (2021). Application of Dalbergiella Welwitschii Leaves Extract in the Demulsification of Water-In-Oil Emulsions. Journal of Chemical Society of Nigeria, 46(6).

Chen, G., & Tao, D. (2005). An experimental study of stability of oil–water emulsion. Fuel processing technology, 86(5), 499-508.

Douglas, L. D., Rivera-Gonzalez, N., Cool, N., Bajpayee, A., Udayakantha, M., Liu, G. W., & Banerjee, S. (2022). A materials science perspective of midstream challenges in the utilization of heavy crude oil. ACS omega, 7(2), 1547-1574.

Emuchay, D., Onyekonwu, M. O., Ogolo, N. A., & Ubani, C. (2013). Breaking of emulsions using locally formulated demusifiers. In SPE Nigeria Annual International Conference and Exhibition. OnePetro.

Erfando, T., Cahyani, S. R., & Rita, N. (2019). The utilization of citrus hystrix and citrus limon as an organic demulsifier formulation. In IOP Conference Series: Materials Science and Engineering (Vol. 509, No. 1, p. 012145). IOP Publishing.

Erfando, T., Handoko, D. T., & Khalid, I. (2020, May). Development of Castor Oil as Local Demulsifier to Overcome Water-Oil Emulsion. In IOP Conference Series: Materials Science and Engineering (Vol. 854, No. 1, p. 012013). IOP Publishing.

Erfando, T., Khalid, I., & Bahari, R. (2021). Experimental of alternative demulsifier formulation from corn oil in overcoming water–oil emulsion. Materials Today: Proceedings, 39, 1061-1064.

Faizullayev, S., Adilbekova, A., Kujawski, W., & Mirzaeian, M. (2022). Recent demulsification methods of crude oil emulsions–Brief review. Journal of Petroleum Science and Engineering, 110643.

Farah, M. A., Oliveira, R. C., Caldas, J. N., & Rajagopal, K. (2005). Viscosity of water-in-oil emulsions: Variation with temperature and water volume fraction. Journal of Petroleum Science and Engineering, 48(3-4), 169-184.

Jafari, S. M., Assadpoor, E., He, Y., & Bhandari, B. (2008). Re-coalescence of emulsion droplets during high-energy emulsification. Food hydrocolloids, 22(7), 1191-1202.

Hemmingsen, P. V., Silset, A., Hannisdal, A., & Sjöblom, J. (2005). Emulsions of heavy crude oils. I: Influence of viscosity, temperature, and dilution. Journal of dispersion science and technology, 26(5), 615-627.

Kokal, S. (2005). Crude-oil emulsions: A state-of-the-art review. SPE Production & facilities, 20(01), 5-13.

Li, W., Huang, Q., Wang, W., & Gao, X. (2020). Advances and future challenges of wax removal in pipeline pigging operations on crude oil transportation systems. Energy Technology, 8(6), 1901412.

McClements, D. J., & Jafari, S. M. (2018). Improving emulsion formation, stability and performance using mixed emulsifiers: A review. Advances in colloid and interface science, 251, 55-79.

Mosayebi, A., & Abedini, R. (2013). Using demulsifiers for phase breaking of water/oil emulsion. Petroleum & Coal, 55(1), 26-30.

Ndubuisi, E. C., Metong, B. U., & Odazie, E. C. (2023). Demulsification of Water-In-Oil Emulsions with Locally Formulated Emulsion Breaker for Production Operations.

Okoro, E. E., Nnaji, C. G., Sanni, S. E., Ahuekwe, E. F., & Igwilo, K. C. (2020). Evaluation of a naturally derived waste brown oil extract for demulsification of crude oil emulsion. Energy Exploration & Exploitation, 38(4), 905-922.

Onaizi, S. A. (2022). Effect of salinity on the characteristics, pH-triggered demulsification and rheology of crude oil/water nanoemulsions. Separation and Purification Technology, 281, 119956.

Oriji, A. B., & Appah, D. (2012). Suitability of local demulsifier as an emulsion treating agent in oil and gas production. In SPE Nigeria Annual International Conference and Exhibition (pp. SPE-162989). SPE.

Poteau, S., Argillier, J. F., Langevin, D., Pincet, F., & Perez, E. (2005). Influence of pH on stability and dynamic properties of asphaltenes and other amphiphilic molecules at the oil− water interface. Energy & Fuels, 19(4), 1337-1341.

Rajak, V. K., Singh, I., Kumar, A., & Mandal, A. (2016). Optimization of separation of oil from oil-in-water emulsion by demulsification using different demulsifiers. Petroleum Science and Technology, 34(11-12), 1026-1032.

Saat, M. A., Chin, L. H., & Wong, C. S. (2020). Treatment of crude oil emulsion using coconut oil and its derivative as green demulsifiers. Materials Today: Proceedings, 31, 106-109.

Schramm, L. L. (1992). Fundamentals and applications in the petroleum Industry. Adv. Chem, 231, 3-24.

Sjoblom, J. (2005). An experimental and theoretical approach to the dynamic behavior of emulsions. In Emulsions and emulsion stability (pp. 21-126). CRC Press.

Sulaiman, A. D., Abdulsalam, S., & Francis, A. O. (2015). Formulation of demulsifiers from locally sourced raw materials for treatment of a typical nigerian crude oil emulsion. In SPE Nigeria Annual International Conference and Exhibition (pp. SPE-178377). SPE.

Udonne, J. D. (2012). Chemical treatment of emulsion problem in crude oil production. Journal of Petroleum and Gas Engineering, 7(3), 135-141.

Yaakob, A. B., & Sulaimon, A. A. (2017). Performance assessment of plant extracts as green demulsifiers. Journal of the Japan Petroleum Institute, 60(4), 186-193.

Zhang, W., Xiao, P., & Wang, D. (2014). Central treatment of different emulsion wastewaters by an integrated process of physicochemically enhanced ultrafiltration and anaerobic–aerobic biofilm reactor. Bioresource technology, 159, 150-156.

Wang, B., Gu, D., Ji, L., & Wu, H. (2016). Photocatalysis: a novel approach to efficient demulsification. Catalysis Communications, 75, 83-86.

Wong, S. F., Lim, J. S., & Dol, S. S. (2015). Crude oil emulsion: A review on formation, classification and stability of water-in-oil emulsions. Journal of Petroleum Science and Engineering, 135, 498-504.

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Published

2025-05-24

Issue

Section

CJET Volume 4 Issue 1

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